1. Introduction The growing demand for advanced energy storage systems, emphasizing high safety and energy density, has driven the evolution of lithium metal batteries (LMBs) from liquid-based electrolytes to solid-state electrolytes (SSEs) in recent years.
SSEs can effectively reduce the risks of batteries associated with thermal runaway and combustion, and mitigate the formation of lithium dendrites , , , , . Moreover, they enable the potential use of lithium metal as the negative electrode, thus further increasing the energy density of the battery , , , , .
Li metal batteries employing this SSE paired with LiFePO 4 cathodes show 81.56 % capacity retention after 800 cycles at 2 C, demonstrating its potential for commercial solid-state batteries. These findings hold promise for advancing the commercialization of composite electrolytes for solid state batteries. 1. Introduction
Several typical properties are needed to meet the demand for developing high-performance solid-state lithium metal batteries. First, high ionic conductivity (>10 −4 S/cm) is required to ensure favorable electrochemical performance , .
Stable interface is formed on the lithium anode by the synergistic effect of LATSP and TMPTA. Li||Li symmetric and Li||LiFePO 4 cells with LATSP@PP-PVC exhibit superior electrochemical performances.
Similarly, the C1s spectrum of the lithium anode cycled with cellulose-PVC electrolyte has three peaks at 284.8 eV (C-C), 286.4 eV (C-O) and 288.8 eV (C = O). However, the C-O signal intensity was significantly enhanced compared to the lithium anode with LATSP@PP-PVC electrolyte, which can be attributed to increased decomposition products.
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